Empirical Formulas
-Empirical formulas are the simplest formula of a compound
-They show only the simplest ratios, not the actual number of atoms
-Molecular formulas give the actual number of atoms
-To determine the empirical formula we need to know the ratio of each element
Example: A sample of an unknown compound is found to contain 8.4 g of Carbon 2.1g of Hydrogen and 5.6g of Oxygen. Determine the empirical formula:
Atom / Mass/ Molar Mass/ Moles/ Mole - Smallest Mole/ Ratio
C / 8.4g/ 12.0 / 0.7 / 2 / 2 > C(2)
H / 2.1g/ 1.0 / 2.1 / 6 / 6 > H(6)
O / 5.6g/ 16.0 / 0.35 / 1 / 1 > O (1)
C2 H6 O = Empirical Formula
The simplest ratio may be decimals. For certain decimals you need to multiply by a certain number.
Decimal Multiplying Co-efficient
0.5 2
0.33 or 0.66 3
0.25 or 0.75 4
0.2, 0.4, 0.6, 0.8 5
Molecular Formulas
-If you know an empirical formula, to find the molecular formula you need the molar mass
Example:
The empirical formula for a substance is CH2O
and its molar mass os 60.0g/mol. Determine the molecular formula
Empirical Molecular
CH2O >>>x2>>>> C2H4O2
30.0 g/mol >>>x2>> 60.0 g/mol
Jomar Delos Santos